Sulfide solid electrolytes are promising materials for next-generation all-solid-state lithium batteries due to their high ionic conductivity, mechanical properties, and compatibility with advanced electrodes like lithium metal.
The electrochemical and physical properties of sulfide electrolytes used for lithium (Li) metal and particle-type anode materials are presented, as well as strategies for mitigating interfacial failures in solid-state cells through interlayer and electrode design.
Sulfide-based SEs are promising candidates for solid-state batteries due to their high lithium-ion conductivity and good interface compatibility with lithium metal anodes .
The ultimate goal of optimizing the sulfide solid-state electrolyte and lithium anode interface is to enhance the stability and energy density of sulfide-based ASSLB, making them suitable for practical applications.
While the sulfide solid electrolyte acts as an ion conductor, the lithium anode serves as a mixed conductor of electrons and ions, allowing for the elimination of lithium ions at the electrode, thereby diminishing the space charge layer at the anode side.
The modified electrolyte materials exhibited stable cycling performance and effectively suppressed the growth of lithium dendrites, thereby improving the compatibility between lithium metal anode and sulfide SE.
Understanding Interfaces at the Positive and Negative Electrodes on Sulfide-Based Solid-State Batteries. ACS Applied Energy Materials 2023, 6 (21), 11030-11042.
All-solid-state batteries based on sulfide solid electrolytes are potential candidates for applications such as electric vehicles. One of the challenges for the realization …
When a 30-μm-thick Al94.5In5.5 negative electrode is combined with a Li6PS5Cl solid-state electrolyte and a LiNi0.6Mn0.2Co0.2O2-based positive electrode, lab …
When tested in a Swagelok cell configuration with a Li-In negative electrode and a 60 wt% S positive electrode applying an average stack pressure of ~55 MPa, the all-solid …
Owing to the excellent physical safety of solid electrolytes, it is possible to build a battery with high energy density by using high‐energy negative electrode materials and …
The electrochemical and physical properties of sulfide electrolytes used for lithium (Li) metal and particle-type anode materials are presented, as well as strategies for mitigating interfacial failures in solid-state …
Sulfide solid electrolytes are promising materials for next-generation all-solid-state lithium batteries due to their high ionic conductivity, mechanical properties, and compatibility with …
Owing to the excellent physical safety of solid electrolytes, it is possible to build a battery with high energy density by using high-energy negative electrode materials and …
Currently, the most promising choice for anode materials in sulfide-based solid-state batteries is lithium metal. However, when lithium metal is used as the anode, its …
Wang, Y. et al. Facile design of sulfide‐based all solid‐state lithium metal battery: In situ polymerization within self‐supported porous argyrodite skeleton. Adv. Funct. …
All-solid-state Li-metal batteries. The utilization of SEs allows for using Li metal as the anode, which shows high theoretical specific capacity of 3860 mAh g −1, high energy …
cal properties of sulfide electrolytes use d for lithium (Li) metal and particle-type anode materials are presented, as well as strategies for mitigating interfacial failures in solid-state cells …
Currently, the most promising choice for anode materials in sulfide-based solid-state batteries is lithium metal. However, when lithium metal is used as the anode, its …
The electrochemical and physical properties of sulfide electrolytes used for lithium (Li) metal and particle-type anode materials are presented, as well as strategies for …
In this study, we present the successful implementation of a Li[Ni,Co,Mn]O2 material with high nickel content (LiNi0.8Co0.1Mn0.1O2, NCM-811) in a bulk-type solid-state battery with β-Li3PS4 as a sulfide-based solid …
Since the inorganic solid electrolyte is a solid rather than a liquid, the combination of all-solid-state LIBs and Si negative electrode can mechanically suppress the …
This study quantifies the extent of this variability by providing commercially sourced battery materials—LiNi0.6Mn0.2Co0.2O2 for the positive electrode, Li6PS5Cl as the …
Owing to the excellent physical safety of solid electrolytes, it is possible to build a battery with high energy density by using high-energy negative electrode materials and …