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Defect is unavoidable in solution-processed Tin-based perovskite compounds. Defect plays an important role in the photovoltaic parameters and stability of Tin-based perovskites and their devices. Tin-based perovskite solar cells have exhibited great potential for their small bandgap, high carrier mobility, and non-toxic property.
Tin (Sn) -based perovskite solar cells (PSCs) normally show low open circuit voltage due to serious carrier recombination in the devices, which can be attributed to the oxidation and the resultant high p-type doping of the perovskite active layers.
The use of doped semiconductors in heterojunction solar cells has improved device performance significantly by shifting the energy levels of the electron and hole transport layers.
Adv. Energy Mater. 8, 1702019 (2017). Wang, F. et al. 2D-quasi-2D-3D hierarchy structure for tin perovskite solar cells with enhanced efficiency and stability. Joule 2, 2732–2743 (2018). Li, M. et al. Tin halide perovskite films made of highly oriented 2D crystals enable more efficient and stable lead-free perovskite solar cells.
Consequently, tin oxidation and its corresponding defective behavior seriously affect the device photovoltaic performance including output photovoltage and power conversion efficiency. We summarize these methods to suppress tin oxidation, such as tin halide compensation, reducing agents, composition and morphology optimization, and encapsulation.
It is found that the doping density of the electron transport layer (TiO 2) and absorber layer (CsSnI 3) has a significant effect on the band alignment and thus on the device performance; however, an increase in the acceptor doping density of the hole transport layer (CuSCN) does not make any significant changes in the device performance.
P-type self-doping is known to hamper tin-based perovskites for developing high-performance solar cells by increasing the background current density and carrier …
Photovoltaic performance in CIGS solar cells: effects of using Mg- and Al-doped ZnO thin-film layers as alternative TCO and front contact layer ... In contrast, copper …
Commonly used materials include pristine or doped zinc oxide [21, 24, 25] as well as tin oxide for inverted structured solar cells and molybdenum oxide [27, 28] for conventional …
was employed, which resulted in the fabrication of a more stable and efficient tin-based perovskite solar cell [31]. Figure1a,b presents the optoelectronic characterization of an AHP …
Sn-based perovskite solar cells normally show low open circuit voltage due to serious carrier recombination in the devices, which can be attributed to the oxidation and the …
Trivalent antimony is used to counter-dope the oxidized Sn-based perovskite by replacing divalent tin in the crystal lattice. It effectively decreases the doping levels in tin halide perovskites down...
Advanced Science is a high-impact, interdisciplinary science journal covering materials science, physics, chemistry, medical and life sciences, and engineering. Abstract Tin (Sn)-containing …
Sn-based perovskite solar cells normally show low open circuit voltage due to serious carrier recombination in the devices, which can be attributed to the oxidation and the …
However, the device performance of tin perovskite solar cells has advanced at a slower pace relative to their Pb counterparts, mainly due to their poorer stability under ambient …
The most rapidly expanding type of solar cells are the Perovskite Solar Cells (PSCs), because of its high device performance, ease of synthesis, high open-circuit voltage, …
Tin-based perovskite solar cells have exhibited great potential for their small bandgap, high carrier mobility, and non-toxic property. With an ever-increasing interest in …
P-type self-doping is known to hamper tin-based perovskites for developing high-performance solar cells by increasing the background current density and carrier recombination processes. In this work, we propose a …
All-perovskite tandem solar cells offer promising avenues for increased photovoltaic efficiency. However, the inherent oxidation of tin limits the actual performance of …
The use of doped semiconductors in heterojunction solar cells has improved device performance significantly by shifting the energy levels of the electron and hole transport …
A silicon reference solar cell (PVM1211, NREL_ISO tracking#:1974) was used to set the irradiance at 100 mW cm −2 at standard testing conditions in accordance with IEC …
Tin-based perovskite solar cells have exhibited great potential for their small bandgap, high carrier mobility, and non-toxic property. With an ever-increasing interest in …
In this study, we aimed to improve the electrical, optical, and structural properties of ZnO-based layered CIGS solar cells by doping different ratios of Al and Mg. Al …
As a potential absorber layer for solar cells, tin-based perovskite has drawn interest in photovoltaics. CsSnI3 is a direct band-gap (~1.3 eV) material belonging to the …
The impact of the doping on the V OC is presented in Figure 4a. For the reference cells (with PCBM) ... For the doped solar cells, the highest J SC and FF were achieved for the SmI 2 concentration of 3 mg mL −1, with the …
Lead-containing perovskite solar cell technology is on the verge of commercialization and has huge potential to replace silicon solar cells, but despite the very promising future of these perovskite solar cells, the presence …
Overcoming V oc loss to increase the efficiency of perovskite solar cells (PSCs) has been aggressively studied. In this work, we introduce and compare rubidium iodide (RbI) and …
Lead-containing perovskite solar cell technology is on the verge of commercialization and has huge potential to replace silicon solar cells, but despite the very …
4 · Narrow-bandgap Sn–Pb mixed perovskite solar cells (PSCs) have emerged as a crucial component in the development of high-efficiency all-perovskite tandem solar cells. …
Trivalent antimony is used to counter-dope the oxidized Sn-based perovskite by replacing divalent tin in the crystal lattice. It effectively decreases the doping levels in tin halide …
4 · Narrow-bandgap Sn–Pb mixed perovskite solar cells (PSCs) have emerged as a crucial component in the development of high-efficiency all-perovskite tandem solar cells. …
Employing the usual standard recipe as a baseline, we carefully modified the dopant ratios of tBP and LiTFSI within spiro-OMeTAD, evaluating the performance of …